| 1. Round | 02/02/2013 | Alianza Petrolera | - | Santa Fe | 0:3 |  |
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| 2. Round | 08/02/2013 | La Equidad | - | Alianza Petrolera | 0:1 | |
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| 3. Round | 17/02/2013 | Atlético Nacional | - | Alianza Petrolera | 4:0 | ||||
| 4. Round | 24/02/2013 | Alianza Petrolera | - | Independiente Medellín | 0:1 | ||||
| 5. Round | 02/03/2013 | Itagüi Ditaires | - | Alianza Petrolera | 3:0 | |
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| 14. Round | 04/05/2013 | Atlético Junior | - | Alianza Petrolera | 2:1 | |
Colombia