| 1. Round | 03/08/2013 | KSV Roeselare | - | Royal Mouscron-Péruwelz | 1:1 | ||||
| 2. Round | 10/08/2013 | Royal Mouscron-Péruwelz | - | White Star Bruxelles | 2:1 |  |
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| 3. Round | 30/08/2013 | KFC Dessel Sport | - | Royal Mouscron-Péruwelz | 0:5 | |
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| 4. Round | 04/09/2013 | Eendracht Aalst | - | Royal Mouscron-Péruwelz | 2:3 | ||||
| 5. Round | 07/09/2013 | Royal Mouscron-Péruwelz | - | Royal Antwerp FC | 1:0 | ||||
| 6. Round | 11/09/2013 | Royal Mouscron-Péruwelz | - | KSK Heist | 5:0 | ||||
| 7. Round | 14/09/2013 | ASV Geel | - | Royal Mouscron-Péruwelz | 0:1 | ||||
| 8. Round | 21/09/2013 | Royal Mouscron-Péruwelz | - | Hoogstraten VV | 2:1 |  |
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| 10. Round | 06/10/2013 | AFC Tubize | - | Royal Mouscron-Péruwelz | 0:1 | ||||
| 13. Round | 26/10/2013 | Royal Mouscron-Péruwelz | - | Excelsior Virton | 0:0 | ||||
| 14. Round | 01/11/2013 | Sint-Truidense VV | - | Royal Mouscron-Péruwelz | 2:1 | ||||
| 15. Round | 09/11/2013 | Royal Mouscron-Péruwelz | - | FC Brussels | 0:1 | ||||
| 18. Round | 29/11/2013 | Royal Mouscron-Péruwelz | - | KSV Roeselare | 2:0 |
Croatia
Australia