| 4. Round | 05/08/2012 | Metalurh Donetsk | - | Metalist Kharkiv | 2:2 |  |
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| 8. Round | 01/09/2012 | Karpaty Lviv | - | Metalurh Donetsk | 0:1 | ||||
| 10. Round | 30/09/2012 | Hoverla Uzhgorod | - | Metalurh Donetsk | 2:1 | ||||
| 11. Round | 05/10/2012 | Metalurh Donetsk | - | FK Krivbas (old) | 6:2 | ||||
| 12. Round | 20/10/2012 | Volyn Lutsk | - | Metalurh Donetsk | 1:1 | ||||
| 13. Round | 27/10/2012 | Metalurh Donetsk | - | Vorskla Poltava | 0:0 | ||||
| 15. Round | 11/11/2012 | Metalurh Donetsk | - | Shakhtar Donetsk | 0:4 | ||||
| 18. Round | 01/12/2012 | Metalurh Donetsk | - | Dnipro Dnipropetrovsk | 0:0 |
Armenia