| 1. Round | 10/08/2013 | Valenciennes FC | - | Toulouse FC | 3:0 | ||||
| 3. Round | 24/08/2013 | Valenciennes FC | - | Olympique Marseille | 0:1 | ||||
| 4. Round | 31/08/2013 | FC Lorient | - | Valenciennes FC | 1:0 | ||||
| 5. Round | 14/09/2013 | Valenciennes FC | - | AS Saint-Étienne | 1:3 | ||||
| 7. Round | 25/09/2013 | Valenciennes FC | - | Paris Saint-Germain | 0:1 | ||||
| 9. Round | 05/10/2013 | Valenciennes FC | - | Stade de Reims | 1:1 | ||||
| 18. Round | 15/12/2013 | Girondins Bordeaux | - | Valenciennes FC | 2:1 |
Romania