| 1. Round | 22/07/2000 | Orlen Plock | - | Groclin Dyskobolia | 1:0 | ||||
| 2. Round | 29/07/2000 | Widzew Łódź | - | Orlen Plock | 3:2 | ||||
| 3. Round | 06/08/2000 | Orlen Plock | - | Górnik Zabrze | 1:0 | ||||
| 4. Round | 12/08/2000 | Pogoń Szczecin | - | Orlen Plock | 3:2 | ||||
| 5. Round | 19/08/2000 | Orlen Plock | - | Odra Wodzisław | 1:2 |  |
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| 6. Round | 27/08/2000 | Polonia Warszawa | - | Orlen Plock | 1:0 | |
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| 7. Round | 09/09/2000 | Orlen Plock | - | Stomil Olsztyn | 1:2 | ||||
| 8. Round | 16/09/2000 | GKS Katowice | - | Orlen Plock | 0:0 | ||||
| 9. Round | 30/09/2000 | Orlen Plock | - | Śląsk Wrocław | 2:1 | ||||
| 10. Round | 14/10/2000 | Ruch Chorzów | - | Orlen Plock | 1:1 | ||||
| 11. Round | 21/10/2000 | Orlen Plock | - | Amica Wronki | 2:6 | |
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| 12. Round | 29/10/2000 | Orlen Plock | - | Wisła Kraków | 0:5 | ||||
| 13. Round | 04/11/2000 | Legia Warszawa | - | Orlen Plock | 1:1 | ||||
| 14. Round | 11/11/2000 | Orlen Plock | - | Zagłębie Lubin | 1:3 | ||||
| 15. Round | 18/11/2000 | Ruch Radzionków | - | Orlen Plock | 2:1 | |
Poland