| 5. Round | 23/09/2013 | Espanyol Barcelona | - | Athletic Club | 3:2 | ||||
| 6. Round | 26/09/2013 | Villarreal CF | - | Espanyol Barcelona | 2:1 | ||||
| 7. Round | 29/09/2013 | Espanyol Barcelona | - | Getafe CF | 0:2 | ||||
| 18. Round | 05/01/2014 | CA Osasuna | - | Espanyol Barcelona | 1:0 | ||||
| 37. Round | 11/05/2014 | Espanyol Barcelona | - | CA Osasuna | 1:1 |
Spain