| 1. Round | 22/07/2013 | Slavia Sofia | - | PFC Beroe | 0:2 | ||||
| 3. Round | 03/08/2013 | Slavia Sofia | - | PFC Ludogorets Razgrad | 0:3 | ||||
| 4. Round | 09/08/2013 | Neftochimik Burgas | - | Slavia Sofia | 1:1 | ||||
| 9. Round | 21/09/2013 | Slavia Sofia | - | Lyubimetz 2007 | 1:1 | ||||
| 10. Round | 25/09/2013 | PSFC Chernomorets | - | Slavia Sofia | 2:2 | ||||
| 12. Round | 05/10/2013 | Slavia Sofia | - | CSKA Sofia | 0:1 | ||||
| 14. Round | 25/10/2013 | PFC Beroe | - | Slavia Sofia | 2:1 | ||||
| 17. Round | 09/11/2013 | Slavia Sofia | - | Neftochimik Burgas | 2:0 |  |
|||
| 18. Round | 22/11/2013 | Lokomotiv Sofia | - | Slavia Sofia | 0:1 | ||||
| 19. Round | 01/12/2013 | Slavia Sofia | - | Botev Plovdiv | 1:2 | ||||
| 20. Round | 04/12/2013 | PFC Pirin Gotse Delchev | - | Slavia Sofia | 1:3 | |
|||
| 21. Round | 07/12/2013 | Slavia Sofia | - | PFC Litex Lovech | 1:2 | ||||
| 22. Round | 11/12/2013 | Lyubimetz 2007 | - | Slavia Sofia | 2:2 | |
|||
| 23. Round | 15/12/2013 | Slavia Sofia | - | PSFC Chernomorets | 2:0 | |
|||
| 24. Round | 22/02/2014 | Levski Sofia | - | Slavia Sofia | 2:2 | ||||
| 25. Round | 01/03/2014 | CSKA Sofia | - | Slavia Sofia | 3:0 | ||||
| 26. Round | 09/03/2014 | Slavia Sofia | - | Lokomotiv Plovdiv | 4:1 |
Bulgaria