| 1. Round | 29/07/2006 | Hibernian FC | - | Aberdeen FC | 1:1 | ||||
| 2. Round | 05/08/2006 | Kilmarnock FC | - | Hibernian FC | 2:1 |  |
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| 3. Round | 12/08/2006 | Inverness CT | - | Hibernian FC | 0:0 | ||||
| 5. Round | 26/08/2006 | Celtic FC | - | Hibernian FC | 2:1 | ||||
| 6. Round | 10/09/2006 | Dundee United | - | Hibernian FC | 0:3 |  |
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| 7. Round | 17/09/2006 | Hibernian FC | - | Rangers FC | 2:1 | |
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| 9. Round | 30/09/2006 | St. Mirren FC | - | Hibernian FC | 1:0 | ||||
| 10. Round | 15/10/2006 | Hibernian FC | - | Heart of Midlothian | 2:2 | |
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| 11. Round | 23/10/2006 | Dunfermline Athletic | - | Hibernian FC | 0:4 | |
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| 12. Round | 30/10/2006 | Aberdeen FC | - | Hibernian FC | 2:1 | |
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| 14. Round | 11/11/2006 | Hibernian FC | - | Inverness CT | 2:0 | |
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| 15. Round | 18/11/2006 | Motherwell FC | - | Hibernian FC | 1:6 | |
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| 17. Round | 02/12/2006 | Hibernian FC | - | Dundee United | 2:1 | ||||
| 18. Round | 09/12/2006 | Rangers FC | - | Hibernian FC | 3:0 | ||||
| 20. Round | 23/12/2006 | Hibernian FC | - | St. Mirren FC | 5:1 | |
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| 21. Round | 26/12/2006 | Heart of Midlothian | - | Hibernian FC | 3:2 | |
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| 22. Round | 30/12/2006 | Hibernian FC | - | Dunfermline Athletic | 2:0 | |
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| 23. Round | 02/01/2007 | Hibernian FC | - | Aberdeen FC | 0:0 |
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