| 4. Round | 06/09/2000 | Excelsior Mouscron | - | K.S.C. Eendracht Aalst | 2:0 | ||||
| 8. Round | 29/09/2000 | Excelsior Mouscron | - | RSC Charleroi | 3:0 | ||||
| 10. Round | 21/10/2000 | Excelsior Mouscron | - | RSC Anderlecht | 1:2 | ||||
| 11. Round | 27/10/2000 | Lierse SK (old) | - | Excelsior Mouscron | 1:4 | ||||
| 12. Round | 12/11/2000 | Excelsior Mouscron | - | KRC Genk | 2:0 | ||||
| 13. Round | 18/11/2000 | KAA Gent | - | Excelsior Mouscron | 1:0 |  |
Belgium