| 4. Round | 18/08/2006 | Farul Constanța | - | FC Unirea | 0:1 | ||||
| 5. Round | 25/08/2006 | Ceahlăul Piatra Neamt | - | FC Unirea | 2:1 |  |
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| 6. Round | 10/09/2006 | FC Unirea | - | National Bucureşti | 2:0 | |
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| 7. Round | 16/09/2006 | Pandurii Târgu Jiu | - | FC Unirea | 1:0 | |
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| 8. Round | 20/09/2006 | FC Unirea | - | Jiul Petroşani | 3:0 | ||||
| 9. Round | 23/09/2006 | SC FC Politehnica Timisoara | - | FC Unirea | 1:0 | ||||
| 10. Round | 01/10/2006 | FC Unirea | - | FC Universitatea Craiova | 1:2 | ||||
| 11. Round | 14/10/2006 | UTA Arad | - | FC Unirea | 1:0 | ||||
| 13. Round | 28/10/2006 | FC Steaua Bucureşti | - | FC Unirea | 3:0 | ||||
| 14. Round | 03/11/2006 | FC Unirea | - | Argeș Pitești | 0:0 | ||||
| 15. Round | 11/11/2006 | Rapid Bucureşti | - | FC Unirea | 1:0 | ||||
| 16. Round | 18/11/2006 | FC Unirea | - | Dinamo Bucureşti | 1:1 | ||||
| 17. Round | 24/11/2006 | Gloria Bistrița (old) | - | FC Unirea | 0:0 | ||||
| 18. Round | 01/12/2006 | Politehnica Iasi | - | FC Unirea | 1:3 | ||||
| 19. Round | 10/12/2006 | FC Unirea | - | CFR Cluj | 0:0 |
Romania