| 1. Round | 11/09/2022 | UE Engordany | - | FC Santa Coloma | 0:1 |  |
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| 2. Round | 18/09/2022 | FC Santa Coloma | - | Inter Club d'Escaldes | 2:2 | |
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| 8. Round | 06/11/2022 | Atlétic Escaldes | - | FC Santa Coloma | 0:0 | ||||
| 9. Round | 13/11/2022 | FC Santa Coloma | - | FC Ordino | 1:0 | ||||
| 10. Round | 20/11/2022 | Penya Encarnada | - | FC Santa Coloma | 0:3 | ||||
| 11. Round | 27/11/2022 | FC Santa Coloma | - | UE Engordany | 6:0 | ||||
| 13. Round | 11/12/2022 | FC Santa Coloma | - | UE Santa Coloma | 3:0 | ||||
| 14. Round | 18/12/2022 | Inter Club d'Escaldes | - | FC Santa Coloma | 2:1 | ||||
| 17. Round | 12/02/2023 | UE Santa Coloma | - | FC Santa Coloma | 0:0 | ||||
| 18. Round | 19/02/2023 | FC Santa Coloma | - | Atlétic Escaldes | 0:3 | ||||
| 19. Round | 26/02/2023 | FC Santa Coloma | - | Inter Club d'Escaldes | 1:1 | ||||
| 20. Round | 04/03/2023 | UE Engordany | - | FC Santa Coloma | 0:3 | |
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| 21. Round | 12/03/2023 | FC Santa Coloma | - | UE Sant Julià | 4:0 | |
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| 22. Round | 02/04/2023 | FC Santa Coloma | - | Atlétic Escaldes | 0:1 | ||||
| 23. Round | 16/04/2023 | Inter Club d'Escaldes | - | FC Santa Coloma | 0:0 | ||||
| 28. Round | 19/05/2023 | Penya Encarnada | - | FC Santa Coloma | 2:0 |
Spain