| 7. Round | 28/08/2005 | FK Krivbas (old) | - | Stal Alchevsk | 2:1 | ||||
| 10. Round | 25/09/2005 | Stal Alchevsk | - | Metalurg Zaporizhya | 1:1 | ||||
| 11. Round | 02/10/2005 | Arsenal Kiev | - | Stal Alchevsk | 1:1 | ||||
| 12. Round | 16/10/2005 | Metalist Kharkiv | - | Stal Alchevsk | 1:0 | ||||
| 13. Round | 23/10/2005 | Stal Alchevsk | - | Zakarpattya Uzhgorod | 1:0 | ||||
| 14. Round | 30/10/2005 | FK Illichivets | - | Stal Alchevsk | 3:0 | ||||
| 23. Round | 26/03/2006 | Tavriya Simferopol (1958-2014) | - | Stal Alchevsk | 5:2 | ||||
| 24. Round | 01/04/2006 | Stal Alchevsk | - | Shakhtar Donetsk | 1:3 | ||||
| 25. Round | 08/04/2006 | Metalurg Zaporizhya | - | Stal Alchevsk | 2:1 | ||||
| 27. Round | 22/04/2006 | Stal Alchevsk | - | Metalist Kharkiv | 1:1 | ||||
| 20. Round | 26/04/2006 | Stal Alchevsk | - | Dnipro Dnipropetrovsk | 0:0 |  |
|||
| 28. Round | 29/04/2006 | Zakarpattya Uzhgorod | - | Stal Alchevsk | 0:2 | ||||
| 29. Round | 06/05/2006 | Stal Alchevsk | - | FK Illichivets | 1:0 | |
|||
| 30. Round | 10/05/2006 | Vorskla Poltava | - | Stal Alchevsk | 1:0 |
Ukraine
Russia