| 1. Round | 22/07/2006 | Stal Alchevsk | - | Metalist Kharkiv | 0:1 | ||||
| 2. Round | 30/07/2006 | Metalurh Donetsk | - | Stal Alchevsk | 2:1 | ||||
| 4. Round | 20/08/2006 | Vorskla Poltava | - | Stal Alchevsk | 1:0 | ||||
| 5. Round | 27/08/2006 | Stal Alchevsk | - | Tavriya Simferopol (1958-2014) | 0:1 | ||||
| 6. Round | 10/09/2006 | Dnipro Dnipropetrovsk | - | Stal Alchevsk | 0:0 |  |
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| 7. Round | 16/09/2006 | Stal Alchevsk | - | Arsenal Kiev | 1:1 | ||||
| 8. Round | 24/09/2006 | Stal Alchevsk | - | FK Kharkiv | 4:2 | ||||
| 10. Round | 15/10/2006 | Stal Alchevsk | - | Karpaty Lviv | 0:1 | |
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| 11. Round | 21/10/2006 | Dinamo Kiev | - | Stal Alchevsk | 3:1 | |
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| 12. Round | 29/10/2006 | Stal Alchevsk | - | Chernomorets Odessa | 2:1 | ||||
| 14. Round | 12/11/2006 | Stal Alchevsk | - | FK Krivbas (old) | 0:0 | |
Ukraine
Russia