| 2. Round | 27/08/2011 | FC Barcelona B | - | Villarreal CF B | 0:2 | ||||
| 3. Round | 03/09/2011 | Villarreal CF B | - | CE Sabadell | 3:4 |  |
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| 4. Round | 10/09/2011 | AD Alcorcón | - | Villarreal CF B | 1:1 | ||||
| 5. Round | 18/09/2011 | Villarreal CF B | - | CD Guadalajara | 3:3 |  |
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| 7. Round | 30/09/2011 | Villarreal CF B | - | Gimnàstic de Tarragona | 3:2 | ||||
| 8. Round | 09/10/2011 | Córdoba CF | - | Villarreal CF B | 1:1 |
France