| 3. Round | 12/08/2006 | Heart of Midlothian | - | Falkirk FC | 0:0 | ||||
| 4. Round | 19/08/2006 | Rangers FC | - | Heart of Midlothian | 2:0 | ||||
| 11. Round | 21/10/2006 | Heart of Midlothian | - | Kilmarnock FC | 0:2 |  |
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| 12. Round | 28/10/2006 | Heart of Midlothian | - | Dunfermline Athletic | 1:1 | ||||
| 17. Round | 02/12/2006 | St. Mirren FC | - | Heart of Midlothian | 2:2 | ||||
| 18. Round | 09/12/2006 | Heart of Midlothian | - | Motherwell FC | 4:1 | ||||
| 19. Round | 16/12/2006 | Heart of Midlothian | - | Aberdeen FC | 0:1 | ||||
| 20. Round | 23/12/2006 | Dundee United | - | Heart of Midlothian | 0:1 | ||||
| 21. Round | 26/12/2006 | Heart of Midlothian | - | Hibernian FC | 3:2 |  |
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| 27. Round | 10/02/2007 | Heart of Midlothian | - | Inverness CT | 1:0 | ||||
| 29. Round | 05/03/2007 | Motherwell FC | - | Heart of Midlothian | 0:2 | ||||
| 30. Round | 10/03/2007 | Aberdeen FC | - | Heart of Midlothian | 1:0 | |
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| 31. Round | 17/03/2007 | Heart of Midlothian | - | Dundee United | 0:4 |
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