| 6. Round | 10/09/1999 | Montpellier HSC | - | Olympique Marseille | 3:1 | ||||
| 7. Round | 18/09/1999 | AS Nancy Lorraine | - | Montpellier HSC | 1:2 | ||||
| 8. Round | 24/09/1999 | Montpellier HSC | - | CS Sedan | 1:1 |  |
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| 9. Round | 01/10/1999 | Havre AC | - | Montpellier HSC | 2:1 | ||||
| 10. Round | 12/10/1999 | Montpellier HSC | - | AS Saint-Étienne | 0:1 | |
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| 11. Round | 15/10/1999 | RC Lens | - | Montpellier HSC | 1:0 | ||||
| 12. Round | 23/10/1999 | Montpellier HSC | - | SC Bastia | 1:1 | ||||
| 13. Round | 29/10/1999 | AJ Auxerre | - | Montpellier HSC | 2:1 | ||||
| 14. Round | 06/11/1999 | ATAC Troyes | - | Montpellier HSC | 2:1 | ||||
| 17. Round | 26/11/1999 | Montpellier HSC | - | Paris Saint-Germain | 0:1 | ||||
| 19. Round | 10/12/1999 | Montpellier HSC | - | RC Strasbourg | 1:1 | ||||
| 20. Round | 17/12/1999 | AS Monaco | - | Montpellier HSC | 1:0 | |
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| 23. Round | 25/01/2000 | Montpellier HSC | - | AS Nancy Lorraine | 1:0 | ||||
| 24. Round | 01/02/2000 | CS Sedan | - | Montpellier HSC | 2:1 | |
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| 26. Round | 15/02/2000 | AS Saint-Étienne | - | Montpellier HSC | 5:4 |
France