| 1. Round | 17/08/2013 | Real Valladolid | - | Athletic Club | 1:2 | ||||
| 2. Round | 23/08/2013 | Athletic Club | - | CA Osasuna | 2:0 | ||||
| 3. Round | 01/09/2013 | Real Madrid | - | Athletic Club | 3:1 | ||||
| 4. Round | 16/09/2013 | Athletic Club | - | RC Celta | 3:2 | ||||
| 12. Round | 03/11/2013 | Atlético Madrid | - | Athletic Club | 2:0 |  |
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| 20. Round | 20/01/2014 | Athletic Club | - | Real Valladolid | 4:2 |  |
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| 24. Round | 16/02/2014 | Athletic Club | - | Espanyol Barcelona | 1:2 | ||||
| 30. Round | 25/03/2014 | Elche CF | - | Athletic Club | 0:0 | ||||
| 32. Round | 07/04/2014 | Levante UD | - | Athletic Club | 1:2 | |
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| 33. Round | 14/04/2014 | Athletic Club | - | Málaga CF | 3:0 | ||||
| 34. Round | 20/04/2014 | FC Barcelona | - | Athletic Club | 2:1 | ||||
| 35. Round | 27/04/2014 | Athletic Club | - | Sevilla FC | 3:1 | ||||
| 36. Round | 02/05/2014 | Rayo Vallecano | - | Athletic Club | 0:3 | ||||
| 38. Round | 18/05/2014 | UD Almería | - | Athletic Club | 0:0 | |
Spain