| 1. Round | 31/07/2013 | Santa Fe | - | Alianza Petrolera | 2:2 |  |
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| 4. Round | 18/08/2013 | Independiente Medellín | - | Alianza Petrolera | 0:1 | ||||
| 6. Round | 26/08/2013 | Envigado FC | - | Alianza Petrolera | 0:0 | ||||
| 7. Round | 28/08/2013 | Alianza Petrolera | - | Deportes Quindío | 1:1 |  |
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| 5. Round | 08/09/2013 | Alianza Petrolera | - | Itagüi Ditaires | 1:0 | |
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| 9. Round | 14/09/2013 | La Equidad | - | Alianza Petrolera | 4:0 | |
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| 10. Round | 21/09/2013 | Alianza Petrolera | - | Patriotas FC | 0:0 |  |
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| 14. Round | 05/10/2013 | Alianza Petrolera | - | Atlético Junior | 1:1 | ||||
| 17. Round | 02/11/2013 | Atlético Huila | - | Alianza Petrolera | 2:0 |
Colombia