| 1. Round | 26/08/2012 | PAOK Saloniki | - | Panthrakikos | 1:0 | ||||
| 3. Round | 16/09/2012 | PAOK Saloniki | - | Asteras Tripolis | 2:1 | ||||
| 4. Round | 22/09/2012 | Skoda Xanthi | - | PAOK Saloniki | 0:3 |  |
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| 5. Round | 30/09/2012 | PAOK Saloniki | - | Aris Saloniki | 4:1 |  |
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| 7. Round | 20/10/2012 | PAOK Saloniki | - | AEK Athen | 1:0 | ||||
| 8. Round | 27/10/2012 | AO Kerkyra | - | PAOK Saloniki | 0:0 | ||||
| 9. Round | 04/11/2012 | Panionios GSS | - | PAOK Saloniki | 1:2 | ||||
| 10. Round | 11/11/2012 | PAOK Saloniki | - | Platanias Chanion | 2:0 | ||||
| 11. Round | 18/11/2012 | Panathinaikos | - | PAOK Saloniki | 2:0 | |
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| 12. Round | 25/11/2012 | PAOK Saloniki | - | Olympiakos Piraeus | 1:1 | ||||
| 16. Round | 06/01/2013 | Panthrakikos | - | PAOK Saloniki | 1:4 | |
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| 17. Round | 13/01/2013 | PAOK Saloniki | - | Atromitos | 0:0 | ||||
| 18. Round | 19/01/2013 | Asteras Tripolis | - | PAOK Saloniki | 1:0 | |
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| 19. Round | 27/01/2013 | PAOK Saloniki | - | Skoda Xanthi | 0:1 | ||||
| 20. Round | 03/02/2013 | Aris Saloniki | - | PAOK Saloniki | 2:2 | ||||
| 21. Round | 09/02/2013 | PAOK Saloniki | - | OFI Heraklion | 3:1 | |
Greece