| 13. Round | 09/11/2013 | Athletic Club | - | Levante UD | 2:1 | ||||
| 14. Round | 25/11/2013 | Málaga CF | - | Athletic Club | 1:2 | ||||
| 25. Round | 23/02/2014 | Real Betis | - | Athletic Club | 0:2 |  |
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| 26. Round | 28/02/2014 | Athletic Club | - | Granada CF | 4:0 | ||||
| 27. Round | 09/03/2014 | Valencia CF | - | Athletic Club | 1:1 | ||||
| 29. Round | 22/03/2014 | Athletic Club | - | Getafe CF | 1:0 | ||||
| 31. Round | 29/03/2014 | Athletic Club | - | Atlético Madrid | 1:2 | ||||
| 36. Round | 02/05/2014 | Rayo Vallecano | - | Athletic Club | 0:3 | ||||
| 38. Round | 18/05/2014 | UD Almería | - | Athletic Club | 0:0 |
Spain