| 1. Round | 28/07/2012 | KV Mechelen | - | Sporting Charleroi | 4:2 | ||||
| 2. Round | 04/08/2012 | Sporting Charleroi | - | Club Brugge KV | 0:1 | ||||
| 3. Round | 11/08/2012 | KV Kortrijk | - | Sporting Charleroi | 0:1 |  |
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| 4. Round | 19/08/2012 | Sporting Charleroi | - | Standard Liège | 2:6 |  |
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| 5. Round | 25/08/2012 | Beerschot AC | - | Sporting Charleroi | 2:0 | ||||
| 6. Round | 01/09/2012 | Sporting Charleroi | - | KAA Gent | 1:1 | ||||
| 7. Round | 15/09/2012 | RAEC Mons | - | Sporting Charleroi | 2:3 | |
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| 8. Round | 23/09/2012 | Sporting Charleroi | - | KRC Genk | 1:2 | ||||
| 9. Round | 29/09/2012 | Cercle Brugge | - | Sporting Charleroi | 1:0 | ||||
| 10. Round | 06/10/2012 | Sporting Charleroi | - | Oud-Heverlee Leuven | 0:4 | ||||
| 11. Round | 20/10/2012 | Lierse SK (old) | - | Sporting Charleroi | 0:1 | ||||
| 12. Round | 27/10/2012 | Sporting Charleroi | - | RSC Anderlecht | 2:0 | ||||
| 14. Round | 03/11/2012 | Sporting Charleroi | - | Sporting Lokeren | 0:2 | ||||
| 18. Round | 01/12/2012 | Sporting Charleroi | - | KV Kortrijk | 2:0 | ||||
| 19. Round | 07/12/2012 | Standard Liège | - | Sporting Charleroi | 6:1 | ||||
| 20. Round | 15/12/2012 | Sporting Charleroi | - | Beerschot AC | 1:0 |
France
Ivory Coast