| 22. Round | 02/02/2014 | Calcio Catania | - | AS Livorno | 3:3 | ||||
| 23. Round | 09/02/2014 | AS Livorno | - | Genoa CFC | 0:1 | ||||
| 24. Round | 16/02/2014 | Cagliari Calcio | - | AS Livorno | 1:2 | ||||
| 25. Round | 23/02/2014 | AS Livorno | - | Hellas Verona | 2:3 | ||||
| 26. Round | 02/03/2014 | AS Livorno | - | SSC Napoli | 1:1 | ||||
| 27. Round | 09/03/2014 | Sampdoria | - | AS Livorno | 4:2 | ||||
| 28. Round | 16/03/2014 | AS Livorno | - | Bologna FC | 2:1 | ||||
| 29. Round | 22/03/2014 | Torino FC | - | AS Livorno | 3:1 | ||||
| 30. Round | 26/03/2014 | Atalanta | - | AS Livorno | 2:0 | ||||
| 31. Round | 31/03/2014 | AS Livorno | - | Inter | 2:2 | ||||
| 32. Round | 07/04/2014 | Juventus | - | AS Livorno | 2:0 | ||||
| 33. Round | 13/04/2014 | AS Livorno | - | Chievo Verona | 2:4 | ||||
| 34. Round | 19/04/2014 | AC Milan | - | AS Livorno | 3:0 | ||||
| 35. Round | 27/04/2014 | AS Livorno | - | Lazio Roma | 0:2 | ||||
| 36. Round | 04/05/2014 | Udinese Calcio | - | AS Livorno | 5:3 | ||||
| 37. Round | 11/05/2014 | AS Livorno | - | ACF Fiorentina | 0:1 |  |
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| 38. Round | 18/05/2014 | Parma FC | - | AS Livorno | 2:0 |
Algeria
France 
