| 1. Round | 11/08/2012 | Botev Plovdiv | - | Slavia Sofia | 3:0 |  |
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| 5. Round | 15/09/2012 | PFC Pirin Gotse Delchev | - | Slavia Sofia | 0:3 | ||||
| 7. Round | 29/09/2012 | PFC Litex Lovech | - | Slavia Sofia | 5:0 | ||||
| 8. Round | 06/10/2012 | Slavia Sofia | - | CSKA Sofia | 0:2 | ||||
| 9. Round | 21/10/2012 | Lokomotiv Plovdiv | - | Slavia Sofia | 1:0 | ||||
| 10. Round | 27/10/2012 | Slavia Sofia | - | Minyor Pernik | 0:0 | ||||
| 12. Round | 10/11/2012 | Slavia Sofia | - | PFC Ludogorets Razgrad | 0:0 | ||||
| 14. Round | 28/11/2012 | PSFC Chernomorets | - | Slavia Sofia | 2:0 |
Bulgaria