| 1. Round | 13/02/2005 | Colón de Santa Fe | - | River Plate | 2:3 | ||||
| 2. Round | 20/02/2005 | River Plate | - | Banfield | 1:0 | ||||
| 3. Round | 27/02/2005 | Argentinos Juniors | - | River Plate | 3:3 | ||||
| 8. Round | 10/04/2005 | Newell's Old Boys | - | River Plate | 4:2 | ||||
| 9. Round | 17/04/2005 | River Plate | - | Quilmes | 4:0 | ||||
| 10. Round | 24/04/2005 | Almagro | - | River Plate | 2:5 | ||||
| 14. Round | 22/05/2005 | Boca Juniors | - | River Plate | 2:1 | ||||
| 16. Round | 12/06/2005 | Independiente | - | River Plate | 1:1 |  |
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| 17. Round | 19/06/2005 | River Plate | - | Vélez Sarsfield | 0:1 | |
Colombia