| 2. Round | 11/08/2007 | Sint-Truidense VV | - | Excelsior Mouscron | 0:2 | ||||
| 3. Round | 18/08/2007 | Excelsior Mouscron | - | RAEC Mons | 3:1 | ||||
| 4. Round | 25/08/2007 | KVC Westerlo | - | Excelsior Mouscron | 0:2 | ||||
| 5. Round | 02/09/2007 | Excelsior Mouscron | - | RSC Anderlecht | 1:2 | ||||
| 6. Round | 15/09/2007 | KV Mechelen | - | Excelsior Mouscron | 2:2 | ||||
| 7. Round | 22/09/2007 | Excelsior Mouscron | - | Sporting Lokeren | 2:0 | ||||
| 8. Round | 29/09/2007 | Club Brugge KV | - | Excelsior Mouscron | 1:0 | ||||
| 9. Round | 05/10/2007 | Sporting Charleroi | - | Excelsior Mouscron | 1:3 |  |
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| 10. Round | 20/10/2007 | Excelsior Mouscron | - | KRC Genk | 1:1 | ||||
| 11. Round | 27/10/2007 | FCV Dender EH | - | Excelsior Mouscron | 0:3 | |
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| 12. Round | 02/11/2007 | Excelsior Mouscron | - | Standard Liège | 0:0 | ||||
| 13. Round | 10/11/2007 | SV Zulte Waregem | - | Excelsior Mouscron | 2:1 |  |
Belgium