| 1. Round | 08/08/1990 | Borussia Dortmund | - | VfB Stuttgart | 0:3 | ||||
| 2. Round | 17/08/1990 | VfB Stuttgart | - | Hertha BSC | 4:0 |  |
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| 3. Round | 25/08/1990 | Bayern München | - | VfB Stuttgart | 2:1 | ||||
| 4. Round | 01/09/1990 | VfB Stuttgart | - | 1. FC Nürnberg | 2:1 | ||||
| 5. Round | 07/09/1990 | Bayer 05 Uerdingen | - | VfB Stuttgart | 2:0 | ||||
| 6. Round | 15/09/1990 | VfB Stuttgart | - | Bayer Leverkusen | 0:2 | ||||
| 7. Round | 22/09/1990 | FC St. Pauli | - | VfB Stuttgart | 2:2 | ||||
| 8. Round | 29/09/1990 | VfB Stuttgart | - | SG Wattenscheid 09 | 1:4 | ||||
| 11. Round | 20/10/1990 | VfB Stuttgart | - | Fortuna Düsseldorf | 1:1 | ||||
| 12. Round | 26/10/1990 | VfL Bochum | - | VfB Stuttgart | 1:1 | ||||
| 13. Round | 10/11/1990 | VfB Stuttgart | - | Werder Bremen | 0:1 | ||||
| 14. Round | 17/11/1990 | Bor. Mönchengladbach | - | VfB Stuttgart | 2:0 | ||||
| 18. Round | 23/02/1991 | VfB Stuttgart | - | Borussia Dortmund | 7:0 | ||||
| 19. Round | 02/03/1991 | Hertha BSC | - | VfB Stuttgart | 0:2 | ||||
| 20. Round | 09/03/1991 | VfB Stuttgart | - | Bayern München | 0:3 | |
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| 33. Round | 08/06/1991 | VfB Stuttgart | - | Hamburger SV | 2:0 |
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