| 3. Round | 28/07/2019 | Santa Fe | - | Alianza Petrolera | 0:1 | ||||
| 5. Round | 10/08/2019 | Once Caldas | - | Alianza Petrolera | 0:0 | ||||
| 6. Round | 18/08/2019 | Alianza Petrolera | - | Atlético Bucaramanga | 1:0 |  |
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| 11. Round | 18/09/2019 | Deportivo Cali | - | Alianza Petrolera | 0:1 | |
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| 12. Round | 22/09/2019 | Alianza Petrolera | - | Unión Magdalena | 1:0 | |
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| 13. Round | 27/09/2019 | Millonarios | - | Alianza Petrolera | 2:1 | ||||
| 14. Round | 02/10/2019 | Alianza Petrolera | - | Atlético Nacional | 0:0 | |
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| 15. Round | 06/10/2019 | Cúcuta Deportivo | - | Alianza Petrolera | 1:1 | |
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| 16. Round | 09/10/2019 | Alianza Petrolera | - | Deportivo Pasto | 2:2 | ||||
| 17. Round | 12/10/2019 | Alianza Petrolera | - | Deportes Tolima | 0:1 | |
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| 19. Round | 24/10/2019 | Alianza Petrolera | - | Atlético Junior | 0:0 | ||||
| 20. Round | 30/10/2019 | Patriotas FC | - | Alianza Petrolera | 1:1 |
Colombia