| 4. Round | 10/02/2023 | Alianza Petrolera | - | Atlético Huila | 2:0 | ||||
| 5. Round | 18/02/2023 | Envigado FC | - | Alianza Petrolera | 0:0 | ||||
| 6. Round | 27/02/2023 | Alianza Petrolera | - | Independiente Medellín | 0:1 |  |
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| 7. Round | 04/03/2023 | La Equidad | - | Alianza Petrolera | 1:1 | ||||
| 12. Round | 10/04/2023 | Alianza Petrolera | - | Santa Fe | 3:1 | ||||
| 13. Round | 15/04/2023 | Alianza Petrolera | - | Jaguares de Córdoba | 3:0 | |
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| 14. Round | 19/04/2023 | Once Caldas | - | Alianza Petrolera | 1:2 | ||||
| 15. Round | 22/04/2023 | Alianza Petrolera | - | Deportivo Cali | 0:3 | ||||
| 16. Round | 25/04/2023 | Atlético Bucaramanga | - | Alianza Petrolera | 1:1 | ||||
| 17. Round | 30/04/2023 | Alianza Petrolera | - | Águilas Doradas | 2:1 | ||||
| 18. Round | 07/05/2023 | Deportes Tolima | - | Alianza Petrolera | 2:1 | ||||
| 20. Round | 18/05/2023 | Deportivo Pereira | - | Alianza Petrolera | 2:1 |
Colombia