| 1. Round | 16/09/2022 | PSV Eindhoven [Women] | - | sc Heerenveen [Women] | 1:0 | ||||
| 3. Round | 02/10/2022 | PSV Eindhoven [Women] | - | ADO Den Haag [Women] | 1:1 | ||||
| 4. Round | 15/10/2022 | PSV Eindhoven [Women] | - | Fortuna Sittard [Women] | 0:2 | ||||
| 5. Round | 21/10/2022 | FC Twente [Women] | - | PSV Eindhoven [Women] | 3:1 |  |
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| 6. Round | 28/10/2022 | PSV Eindhoven [Women] | - | PEC Zwolle [Women] | 4:0 | ||||
| 7. Round | 04/11/2022 | vv Alkmaar [Women] | - | PSV Eindhoven [Women] | 0:2 | ||||
| 8. Round | 20/11/2022 | AFC Ajax [Women] | - | PSV Eindhoven [Women] | 1:0 | ||||
| 9. Round | 27/11/2022 | PSV Eindhoven [Women] | - | Feyenoord [Women] | 3:1 | ||||
| 10. Round | 04/12/2022 | SBV Excelsior [Women] | - | PSV Eindhoven [Women] | 1:3 | ||||
| 12. Round | 31/01/2023 | PSV Eindhoven [Women] | - | FC Twente [Women] | 0:3 | ||||
| 18. Round | 24/03/2023 | PSV Eindhoven [Women] | - | Telstar [Women] | 6:1 | ||||
| 17. Round | 28/03/2023 | PEC Zwolle [Women] | - | PSV Eindhoven [Women] | 4:0 | ||||
| 20. Round | 21/04/2023 | ADO Den Haag [Women] | - | PSV Eindhoven [Women] | 1:2 | ||||
| 22. Round | 07/05/2023 | sc Heerenveen [Women] | - | PSV Eindhoven [Women] | 0:2 |
Belgium