| 1. Round | 16/08/1991 | RSC Charleroi | - | KFC Germinal Ekeren | 3:1 | ||||
| 2. Round | 20/08/1991 | KSK Beveren | - | RSC Charleroi | 0:0 | ||||
| 3. Round | 27/08/1991 | RSC Charleroi | - | KSV Waregem | 1:2 | ||||
| 4. Round | 31/08/1991 | RWD Molenbeek | - | RSC Charleroi | 1:0 | ||||
| 5. Round | 06/09/1991 | KRC Genk | - | RSC Charleroi | 3:0 | ||||
| 6. Round | 13/09/1991 | RSC Charleroi | - | KV Mechelen | 1:2 | ||||
| 8. Round | 27/09/1991 | RSC Charleroi | - | Standard Liège | 0:2 | ||||
| 9. Round | 05/10/1991 | KAA Gent | - | RSC Charleroi | 0:0 | ||||
| 10. Round | 12/10/1991 | RSC Charleroi | - | Royal Antwerp FC | 0:1 | ||||
| 12. Round | 31/10/1991 | RSC Charleroi | - | RSC Anderlecht | 0:0 | ||||
| 14. Round | 22/11/1991 | RSC Charleroi | - | Lierse SK (old) | 0:0 | ||||
| 20. Round | 25/01/1992 | KSV Waregem | - | RSC Charleroi | 0:1 |
England