| 1. Round | 07/08/1999 | Standard Liège | - | KV Mechelen | 2:1 | ||||
| 2. Round | 14/08/1999 | KVC Westerlo | - | Standard Liège | 2:1 |  |
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| 30. Round | 07/04/2000 | Standard Liège | - | Sporting Lokeren | 1:2 | ||||
| 31. Round | 15/04/2000 | Germinal Beerschot | - | Standard Liège | 2:0 | ||||
| 32. Round | 22/04/2000 | Standard Liège | - | K.S.C. Eendracht Aalst | 3:1 | ||||
| 33. Round | 06/05/2000 | RSC Anderlecht | - | Standard Liège | 2:0 | |
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| 34. Round | 11/05/2000 | Standard Liège | - | KRC Harelbeke | 1:3 |
Belgium