| 1. Round | 13/08/2000 | KRC Harelbeke | - | Standard Liège | 3:4 | ||||
| 13. Round | 18/11/2000 | Lierse SK (old) | - | Standard Liège | 1:1 | ||||
| 15. Round | 02/12/2000 | KAA Gent | - | Standard Liège | 2:1 | ||||
| 16. Round | 08/12/2000 | Standard Liège | - | Excelsior Mouscron | 3:3 | ||||
| 19. Round | 20/01/2001 | RAA La Louviére | - | Standard Liège | 0:4 |  |
|||
| 20. Round | 28/01/2001 | Standard Liège | - | Germinal Beerschot | 1:1 | ||||
| 21. Round | 04/02/2001 | Club Brugge KV | - | Standard Liège | 1:1 |  |
|||
| 22. Round | 11/02/2001 | Standard Liège | - | KV Mechelen | 2:0 | ||||
| 23. Round | 18/02/2001 | K.S.C. Eendracht Aalst | - | Standard Liège | 1:1 | ||||
| 24. Round | 03/03/2001 | Standard Liège | - | Sint-Truidense VV | 1:1 | ||||
| 25. Round | 09/03/2001 | KVC Westerlo | - | Standard Liège | 2:2 | ||||
| 26. Round | 17/03/2001 | Standard Liège | - | KSK Beveren | 4:2 | ||||
| 27. Round | 01/04/2001 | RSC Charleroi | - | Standard Liège | 2:3 | |
|||
| 28. Round | 07/04/2001 | Standard Liège | - | Royal Antwerp FC | 0:1 | ||||
| 29. Round | 13/04/2001 | RSC Anderlecht | - | Standard Liège | 0:0 | |
|||
| 31. Round | 28/04/2001 | KRC Genk | - | Standard Liège | 2:2 | |
|||
| 34. Round | 20/05/2001 | Standard Liège | - | Sporting Lokeren | 0:5 | |
Belgium