| 1. Round | 15/09/2019 | Florentia San Gimignano [Women] | - | ACF Fiorentina [Women] | 2:4 |  |
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| 2. Round | 22/09/2019 | ACF Fiorentina [Women] | - | AS Roma [Women] | 0:2 | ||||
| 3. Round | 12/10/2019 | ACF Fiorentina [Women] | - | UPC Tavagnacco [Women] | 2:1 | |
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| 4. Round | 19/10/2019 | Sassuolo Calcio [Women] | - | ACF Fiorentina [Women] | 1:2 | ||||
| 5. Round | 02/11/2019 | ACF Fiorentina [Women] | - | AC Milan [Women] | 1:1 | ||||
| 6. Round | 16/11/2019 | ASD Pink Bari [Women] | - | ACF Fiorentina [Women] | 0:3 | ||||
| 7. Round | 23/11/2019 | ACF Fiorentina [Women] | - | Hellas Verona [Women] | 4:2 | ||||
| 8. Round | 30/11/2019 | Juventus [Women] | - | ACF Fiorentina [Women] | 1:0 | ||||
| 9. Round | 07/12/2019 | Empoli FC [Women] | - | ACF Fiorentina [Women] | 0:3 | ||||
| 10. Round | 15/12/2019 | ACF Fiorentina [Women] | - | Inter [Women] | 4:0 | ||||
| 11. Round | 11/01/2020 | Orobica Calcio Bergamo [Women] | - | ACF Fiorentina [Women] | 1:4 | |
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| 12. Round | 19/01/2020 | ACF Fiorentina [Women] | - | Florentia San Gimignano [Women] | 6:1 | |
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| 13. Round | 26/01/2020 | AS Roma [Women] | - | ACF Fiorentina [Women] | 2:2 | |
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| 15. Round | 15/02/2020 | ACF Fiorentina [Women] | - | Sassuolo Calcio [Women] | 2:1 |
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