| 1. Round | 29/07/2006 | Sporting Charleroi | - | Lierse SK (old) | 0:0 | ||||
| 6. Round | 16/09/2006 | KSK Beveren | - | Sporting Charleroi | 2:2 | ||||
| 7. Round | 22/09/2006 | Sporting Charleroi | - | RSC Anderlecht | 1:1 | ||||
| 8. Round | 30/09/2006 | RAEC Mons | - | Sporting Charleroi | 1:2 |  |
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| 9. Round | 14/10/2006 | Sporting Charleroi | - | Sint-Truidense VV | 2:1 | ||||
| 13. Round | 19/11/2006 | Sporting Charleroi | - | Excelsior Mouscron | 1:0 | ||||
| 17. Round | 17/12/2006 | SV Zulte Waregem | - | Sporting Charleroi | 1:0 |
Central Afr. Republic
France