| 3. Round | 18/08/2007 | Sporting Charleroi | - | KV Mechelen | 1:0 | ||||
| 5. Round | 31/08/2007 | Sporting Charleroi | - | RAEC Mons | 3:1 |  |
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| 6. Round | 15/09/2007 | Germinal Beerschot | - | Sporting Charleroi | 1:0 | ||||
| 7. Round | 23/09/2007 | Sporting Charleroi | - | Club Brugge KV | 1:1 | ||||
| 9. Round | 05/10/2007 | Sporting Charleroi | - | Excelsior Mouscron | 1:3 |  |
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| 13. Round | 10/11/2007 | KRC Genk | - | Sporting Charleroi | 1:0 | ||||
| 14. Round | 01/12/2007 | Sporting Charleroi | - | SV Zulte Waregem | 2:3 | ||||
| 15. Round | 07/12/2007 | Standard Liège | - | Sporting Charleroi | 5:1 | ||||
| 16. Round | 16/12/2007 | Sporting Charleroi | - | KAA Gent | 1:2 | |
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| 17. Round | 23/12/2007 | Cercle Brugge | - | Sporting Charleroi | 3:1 |
Central Afr. Republic
France