| 1. Round | 01/08/2010 | Cercle Brugge | - | Sporting Charleroi | 1:1 | ||||
| 2. Round | 07/08/2010 | Sporting Charleroi | - | RSC Anderlecht | 0:0 | ||||
| 3. Round | 15/08/2010 | KRC Genk | - | Sporting Charleroi | 5:0 |  |
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| 4. Round | 22/08/2010 | Sporting Charleroi | - | KAA Gent | 1:3 | ||||
| 5. Round | 28/08/2010 | Sporting Charleroi | - | KAS Eupen | 2:0 | |
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| 7. Round | 19/09/2010 | Sporting Charleroi | - | Club Brugge KV | 0:5 |
Belgium
Italy