| League phase | 17/09/2024 | Juventus | - | PSV Eindhoven | 3:1 | ||||
| League phase | 01/10/2024 | PSV Eindhoven | - | Sporting CP | 1:1 | ||||
| League phase | 22/10/2024 | Paris Saint-Germain | - | PSV Eindhoven | 1:1 |  |
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| League phase | 05/11/2024 | PSV Eindhoven | - | Girona FC | 4:0 | |
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| League phase | 27/11/2024 | PSV Eindhoven | - | Shakhtar Donetsk | 3:2 | ||||
| League phase | 10/12/2024 | Stade Brestois 29 | - | PSV Eindhoven | 1:0 | |
Belgium