| 25. Round | 30/01/2013 | Heart of Midlothian | - | Dundee FC | 1:0 | ||||
| 21. Round | 02/02/2013 | Ross County FC | - | Heart of Midlothian | 2:2 |  |
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| 26. Round | 09/02/2013 | Dundee United | - | Heart of Midlothian | 3:1 | |
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| 27. Round | 16/02/2013 | Heart of Midlothian | - | Kilmarnock FC | 0:3 |  |
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| 28. Round | 23/02/2013 | Heart of Midlothian | - | Inverness CT | 2:3 | |
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| 29. Round | 27/02/2013 | St. Mirren FC | - | Heart of Midlothian | 2:0 | ||||
| 24. Round | 02/03/2013 | Heart of Midlothian | - | Motherwell FC | 1:2 | ||||
| 31. Round | 05/03/2013 | Heart of Midlothian | - | St. Johnstone FC | 2:0 | ||||
| 30. Round | 10/03/2013 | Hibernian FC | - | Heart of Midlothian | 0:0 | ||||
| 32. Round | 30/03/2013 | Aberdeen FC | - | Heart of Midlothian | 2:0 | |
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| 33. Round | 06/04/2013 | Heart of Midlothian | - | Ross County FC | 4:2 | |
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England