| 3. Round | 10/08/2013 | Alianza Petrolera | - | Atlético Nacional | 1:2 | ||||
| 4. Round | 18/08/2013 | Independiente Medellín | - | Alianza Petrolera | 0:1 |  |
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| 6. Round | 26/08/2013 | Envigado FC | - | Alianza Petrolera | 0:0 | ||||
| 7. Round | 28/08/2013 | Alianza Petrolera | - | Deportes Quindío | 1:1 | |
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| 8. Round | 02/09/2013 | Once Caldas | - | Alianza Petrolera | 1:1 | ||||
| 5. Round | 08/09/2013 | Alianza Petrolera | - | Itagüi Ditaires | 1:0 |  |
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| 11. Round | 27/09/2013 | Boyacá Chicó | - | Alianza Petrolera | 1:2 | |
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| 12. Round | 29/09/2013 | Alianza Petrolera | - | Deportivo Cali | 0:2 | |
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| 13. Round | 03/10/2013 | Deportivo Pasto | - | Alianza Petrolera | 2:1 |  |
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| 14. Round | 05/10/2013 | Alianza Petrolera | - | Atlético Junior | 1:1 | ||||
| 15. Round | 20/10/2013 | Cúcuta Deportivo | - | Alianza Petrolera | 2:0 | ||||
| 17. Round | 02/11/2013 | Atlético Huila | - | Alianza Petrolera | 2:0 | |
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