| 1. Round | 26/07/2013 | Club Brugge KV | - | Sporting Charleroi | 2:0 | ||||
| 3. Round | 10/08/2013 | RAEC Mons | - | Sporting Charleroi | 1:2 |  |
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| 4. Round | 17/08/2013 | Sporting Charleroi | - | KV Kortrijk | 1:2 | ||||
| 5. Round | 25/08/2013 | RSC Anderlecht | - | Sporting Charleroi | 5:2 | |
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| 6. Round | 01/09/2013 | Sporting Charleroi | - | KRC Genk | 1:1 | ||||
| 7. Round | 14/09/2013 | Oud-Heverlee Leuven | - | Sporting Charleroi | 0:0 | ||||
| 9. Round | 28/09/2013 | KV Oostende | - | Sporting Charleroi | 1:0 | ||||
| 10. Round | 05/10/2013 | Sporting Charleroi | - | Sporting Lokeren | 2:1 | ||||
| 14. Round | 02/11/2013 | Lierse SK (old) | - | Sporting Charleroi | 2:1 | ||||
| 15. Round | 09/11/2013 | Sporting Charleroi | - | KAA Gent | 0:1 | ||||
| 18. Round | 07/12/2013 | KV Kortrijk | - | Sporting Charleroi | 1:1 | ||||
| 20. Round | 21/12/2013 | Sporting Charleroi | - | RAEC Mons | 0:2 | ||||
| 21. Round | 26/12/2013 | KRC Genk | - | Sporting Charleroi | 0:3 | ||||
| 22. Round | 18/01/2014 | Sporting Charleroi | - | Oud-Heverlee Leuven | 2:0 | ||||
| 23. Round | 25/01/2014 | Cercle Brugge | - | Sporting Charleroi | 3:0 | ||||
| 24. Round | 01/02/2014 | Sporting Charleroi | - | KV Oostende | 0:1 | ||||
| 30. Round | 16/03/2014 | KV Mechelen | - | Sporting Charleroi | 0:3 |
Senegal