| 1. Round | 02/08/2009 | Sporting Charleroi | - | Club Brugge KV | 1:2 | ||||
| 2. Round | 08/08/2009 | Sint-Truidense VV | - | Sporting Charleroi | 0:0 | ||||
| 3. Round | 16/08/2009 | Sporting Charleroi | - | Germinal Beerschot | 1:0 | ||||
| 4. Round | 21/08/2009 | Standard Liège | - | Sporting Charleroi | 1:1 | ||||
| 5. Round | 29/08/2009 | KSV Roeselare | - | Sporting Charleroi | 1:3 | ||||
| 6. Round | 12/09/2009 | Sporting Charleroi | - | Cercle Brugge | 0:4 | ||||
| 8. Round | 23/09/2009 | Sporting Charleroi | - | KV Mechelen | 1:2 | ||||
| 9. Round | 26/09/2009 | Sporting Lokeren | - | Sporting Charleroi | 4:1 | ||||
| 10. Round | 03/10/2009 | Sporting Charleroi | - | KV Kortrijk | 3:3 | ||||
| 11. Round | 17/10/2009 | RSC Anderlecht | - | Sporting Charleroi | 2:0 | ||||
| 14. Round | 06/11/2009 | Sporting Charleroi | - | KAA Gent | 0:2 | ||||
| 22. Round | 16/01/2010 | Sporting Charleroi | - | KRC Genk | 1:3 | ||||
| 19. Round | 04/02/2010 | Sporting Charleroi | - | Standard Liège | 2:3 |
Morocco