| 1. Round | 17/08/2011 | Sporting Charleroi | - | KVK Tienen | 2:1 | ||||
| 2. Round | 24/08/2011 | KSV Roeselare | - | Sporting Charleroi | 3:0 | ||||
| 22. Round | 29/01/2012 | KSK Heist | - | Sporting Charleroi | 1:2 | ||||
| 25. Round | 19/02/2012 | Sporting Charleroi | - | RBD Borinage | 2:2 | ||||
| 26. Round | 26/02/2012 | Sporting Charleroi | - | Sportkring Sint-Niklaas | 3:1 | ||||
| 27. Round | 04/03/2012 | Eendracht Aalst | - | Sporting Charleroi | 1:2 | ||||
| 28. Round | 10/03/2012 | Sporting Charleroi | - | Standaard Wetteren | 3:0 | ||||
| 29. Round | 17/03/2012 | Sporting Charleroi | - | KAS Eupen | 3:0 | ||||
| 23. Round | 25/03/2012 | Sporting Charleroi | - | R. White Star Woluwe FC | 2:0 | ||||
| 30. Round | 31/03/2012 | Lommel United | - | Sporting Charleroi | 0:2 | ||||
| 31. Round | 06/04/2012 | CS Visé | - | Sporting Charleroi | 2:2 | ||||
| 24. Round | 11/04/2012 | FC Brussels | - | Sporting Charleroi | 2:3 |  |
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| 32. Round | 16/04/2012 | Sporting Charleroi | - | Royal Antwerp FC | 0:3 |
Algeria
France