4. Round | 22/09/2012 | 1. FSV Mainz 05 | - | FC Augsburg | 2:0 | ||||
5. Round | 25/09/2012 | FC Schalke 04 | - | 1. FSV Mainz 05 | 3:0 | ||||
6. Round | 30/09/2012 | VfL Wolfsburg | - | 1. FSV Mainz 05 | 0:2 | ||||
9. Round | 27/10/2012 | 1. FSV Mainz 05 | - | 1899 Hoffenheim | 3:0 | ||||
11. Round | 09/11/2012 | 1. FSV Mainz 05 | - | 1. FC Nürnberg | 2:1 | ||||
13. Round | 24/11/2012 | 1. FSV Mainz 05 | - | Borussia Dortmund | 1:2 | ||||
30. Round | 20/04/2013 | Borussia Dortmund | - | 1. FSV Mainz 05 | 2:0 | ||||
32. Round | 04/05/2013 | Hannover 96 | - | 1. FSV Mainz 05 | 2:2 |