| 4. Round | 17/10/2020 | Arminia Bielefeld | - | Bayern München | 1:4 | ||||
| 5. Round | 25/10/2020 | VfL Wolfsburg | - | Arminia Bielefeld | 2:1 | ||||
| 7. Round | 07/11/2020 | 1. FC Union Berlin | - | Arminia Bielefeld | 5:0 | ||||
| 8. Round | 21/11/2020 | Arminia Bielefeld | - | Bayer Leverkusen | 1:2 | ||||
| 9. Round | 28/11/2020 | RB Leipzig | - | Arminia Bielefeld | 2:1 | ||||
| 11. Round | 12/12/2020 | SC Freiburg | - | Arminia Bielefeld | 2:0 | ||||
| 13. Round | 19/12/2020 | FC Schalke 04 | - | Arminia Bielefeld | 0:1 | ||||
| 16. Round | 16/01/2021 | 1899 Hoffenheim | - | Arminia Bielefeld | 0:0 | ||||
| 17. Round | 20/01/2021 | Arminia Bielefeld | - | VfB Stuttgart | 3:0 | ||||
| 18. Round | 23/01/2021 | Arminia Bielefeld | - | Eintracht Frankfurt | 1:5 |  |
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| 19. Round | 31/01/2021 | 1. FC Köln | - | Arminia Bielefeld | 3:1 | ||||
| 21. Round | 15/02/2021 | Bayern München | - | Arminia Bielefeld | 3:3 | ||||
| 23. Round | 27/02/2021 | Borussia Dortmund | - | Arminia Bielefeld | 3:0 |
Germany