| 1. Round | 19/09/2021 | UE Engordany | - | CE Carroi | 3:1 | ||||
| 4. Round | 17/10/2021 | UE Sant Julià | - | CE Carroi | 2:0 | ||||
| 5. Round | 24/10/2021 | CE Carroi | - | Inter Club d'Escaldes | 0:2 | ||||
| 6. Round | 31/10/2021 | Atlétic Escaldes | - | CE Carroi | 3:1 | ||||
| 7. Round | 07/11/2021 | CE Carroi | - | UE Santa Coloma | 1:2 | ||||
| 8. Round | 21/11/2021 | CE Carroi | - | UE Engordany | 1:4 | ||||
| 9. Round | 28/11/2021 | FC Ordino | - | CE Carroi | 2:0 |  |
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| 10. Round | 19/12/2021 | FC Santa Coloma | - | CE Carroi | 3:0 | ||||
| 12. Round | 19/01/2022 | Inter Club d'Escaldes | - | CE Carroi | 4:2 | ||||
| 11. Round | 26/01/2022 | CE Carroi | - | UE Sant Julià | 0:6 |
Portugal