| 2. Round | 04/08/2013 | Alianza Petrolera | - | La Equidad | 1:2 | ||||
| 3. Round | 10/08/2013 | Alianza Petrolera | - | Atlético Nacional | 1:2 |  |
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| 4. Round | 18/08/2013 | Independiente Medellín | - | Alianza Petrolera | 0:1 | ||||
| 6. Round | 26/08/2013 | Envigado FC | - | Alianza Petrolera | 0:0 | ||||
| 7. Round | 28/08/2013 | Alianza Petrolera | - | Deportes Quindío | 1:1 | |
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| 8. Round | 02/09/2013 | Once Caldas | - | Alianza Petrolera | 1:1 | ||||
| 5. Round | 08/09/2013 | Alianza Petrolera | - | Itagüi Ditaires | 1:0 | ||||
| 9. Round | 14/09/2013 | La Equidad | - | Alianza Petrolera | 4:0 | ||||
| 10. Round | 21/09/2013 | Alianza Petrolera | - | Patriotas FC | 0:0 | ||||
| 11. Round | 27/09/2013 | Boyacá Chicó | - | Alianza Petrolera | 1:2 | ||||
| 12. Round | 29/09/2013 | Alianza Petrolera | - | Deportivo Cali | 0:2 | ||||
| 14. Round | 05/10/2013 | Alianza Petrolera | - | Atlético Junior | 1:1 | ||||
| 15. Round | 20/10/2013 | Cúcuta Deportivo | - | Alianza Petrolera | 2:0 | ||||
| 16. Round | 26/10/2013 | Alianza Petrolera | - | Deportes Tolima | 2:1 | ||||
| 18. Round | 09/11/2013 | Alianza Petrolera | - | Millonarios | 0:1 | |
Colombia