| 2. Round | 01/02/2014 | Alianza Petrolera | - | Boyacá Chicó | 1:2 | ||||
| 3. Round | 06/02/2014 | Atlético Nacional | - | Alianza Petrolera | 5:1 | ||||
| 4. Round | 09/02/2014 | Alianza Petrolera | - | Deportivo Pasto | 1:1 | ||||
| 5. Round | 16/02/2014 | Once Caldas | - | Alianza Petrolera | 2:1 | ||||
| 6. Round | 19/02/2014 | Alianza Petrolera | - | Santa Fe | 1:2 |  |
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| 7. Round | 22/02/2014 | Atlético Huila | - | Alianza Petrolera | 3:0 | ||||
| 8. Round | 27/02/2014 | Alianza Petrolera | - | Atlético Junior | 1:0 | ||||
| 10. Round | 12/03/2014 | Itagüi Ditaires | - | Alianza Petrolera | 1:2 | ||||
| 11. Round | 15/03/2014 | Alianza Petrolera | - | Fortaleza FC | 1:0 | ||||
| 12. Round | 22/03/2014 | Patriotas FC | - | Alianza Petrolera | 3:3 | ||||
| 13. Round | 29/03/2014 | Alianza Petrolera | - | Independiente Medellín | 2:1 | ||||
| 14. Round | 03/04/2014 | Deportivo Cali | - | Alianza Petrolera | 1:2 | ||||
| 15. Round | 05/04/2014 | Uniautónoma FC | - | Alianza Petrolera | 0:2 | ||||
| 16. Round | 08/04/2014 | Alianza Petrolera | - | Millonarios | 2:1 | ||||
| 17. Round | 13/04/2014 | Deportes Tolima | - | Alianza Petrolera | 1:2 | ||||
| 18. Round | 20/04/2014 | Alianza Petrolera | - | Envigado FC | 0:2 |
Colombia