| 1. Round | 13/07/2012 | Volyn Lutsk | - | Karpaty Lviv | 1:1 |  |
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| 2. Round | 22/07/2012 | Volyn Lutsk | - | Vorskla Poltava | 1:0 | ||||
| 3. Round | 28/07/2012 | Chernomorets Odessa | - | Volyn Lutsk | 0:2 | |
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| 4. Round | 06/08/2012 | Volyn Lutsk | - | Shakhtar Donetsk | 0:4 | ||||
| 5. Round | 12/08/2012 | Dinamo Kiev | - | Volyn Lutsk | 4:1 | |
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| 6. Round | 19/08/2012 | Volyn Lutsk | - | Zorya Lugansk | 2:2 | |
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| 7. Round | 26/08/2012 | Dnipro Dnipropetrovsk | - | Volyn Lutsk | 2:1 | ||||
| 19. Round | 01/03/2013 | Shakhtar Donetsk | - | Volyn Lutsk | 4:1 | ||||
| 20. Round | 10/03/2013 | Volyn Lutsk | - | Dinamo Kiev | 0:2 | ||||
| 24. Round | 12/04/2013 | Volyn Lutsk | - | FK Illichivets | 0:2 | ||||
| 25. Round | 21/04/2013 | Tavriya Simferopol (1958-2014) | - | Volyn Lutsk | 3:0 | ||||
| 26. Round | 27/04/2013 | Volyn Lutsk | - | Metalurg Zaporizhya | 0:0 | |
Brazil