| 3. Round | 04/08/2006 | Shakhtar Donetsk | - | Metalist Kharkiv | 5:0 | ||||
| 5. Round | 27/08/2006 | Shakhtar Donetsk | - | FK Illichivets | 3:1 | ||||
| 7. Round | 17/09/2006 | Shakhtar Donetsk | - | Tavriya Simferopol (1958-2014) | 3:0 | ||||
| 9. Round | 01/10/2006 | Shakhtar Donetsk | - | Stal Alchevsk | 3:1 |  |
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| 12. Round | 27/10/2006 | Shakhtar Donetsk | - | Karpaty Lviv | 4:1 | ||||
| 13. Round | 06/11/2006 | Dinamo Kiev | - | Shakhtar Donetsk | 1:0 | ||||
| 14. Round | 11/11/2006 | Shakhtar Donetsk | - | Chernomorets Odessa | 2:0 | ||||
| 15. Round | 18/11/2006 | Metalurg Zaporizhya | - | Shakhtar Donetsk | 0:3 | |
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| 16. Round | 27/11/2006 | FK Krivbas (old) | - | Shakhtar Donetsk | 0:1 | ||||
| 18. Round | 11/03/2007 | Metalist Kharkiv | - | Shakhtar Donetsk | 0:1 | ||||
| 19. Round | 19/03/2007 | Shakhtar Donetsk | - | Metalurh Donetsk | 2:1 | ||||
| 26. Round | 13/05/2007 | Arsenal Kiev | - | Shakhtar Donetsk | 1:2 | |
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| 27. Round | 19/05/2007 | Karpaty Lviv | - | Shakhtar Donetsk | 0:0 | ||||
| 28. Round | 23/05/2007 | Shakhtar Donetsk | - | Dinamo Kiev | 2:2 |
Romania