| 4. Round | 01/09/2012 | Plymouth Argyle | - | Northampton Town | 3:2 |  |
|||
| 9. Round | 29/09/2012 | Plymouth Argyle | - | Southend United | 1:1 | ||||
| 10. Round | 02/10/2012 | Wycombe Wanderers | - | Plymouth Argyle | 1:1 | ||||
| 11. Round | 06/10/2012 | Plymouth Argyle | - | AFC Wimbledon | 1:2 | |
|||
| 12. Round | 13/10/2012 | Barnet FC | - | Plymouth Argyle | 1:4 | |
|||
| 16. Round | 07/11/2012 | Plymouth Argyle | - | Burton Albion | 1:2 | ||||
| 17. Round | 10/11/2012 | Plymouth Argyle | - | Gillingham FC | 2:2 | ||||
| 20. Round | 24/11/2012 | Plymouth Argyle | - | Chesterfield FC | 0:1 | ||||
| 21. Round | 08/12/2012 | Plymouth Argyle | - | York City | 2:0 | ||||
| 22. Round | 15/12/2012 | Exeter City | - | Plymouth Argyle | 1:1 | ||||
| 23. Round | 22/12/2012 | Accrington Stanley | - | Plymouth Argyle | 1:1 | ||||
| 24. Round | 26/12/2012 | Plymouth Argyle | - | Torquay United | 1:1 | ||||
| 25. Round | 29/12/2012 | Plymouth Argyle | - | Wycombe Wanderers | 0:1 | ||||
| 26. Round | 01/01/2013 | Bristol Rovers | - | Plymouth Argyle | 2:1 |
Wales